Annual trace element cycles in calcite–aragonite speleothems: evidence of drought in the western Mediterranean 1200–1100 yr BP     

Emily A. McMillan  Ian J. Fairchild  Silvia Frisia  Andrea Borsato  Frank McDermott 《第四纪科学杂志》2005,20(5):423-433

Each of two calcitic stalagmites from Grotte de Clamouse, Herault, southern France, displays a discrete aragonite layer dated at around 1100 yr BP. The layer of fanning aragonite ray crystals is immediately preceded by calcite with Mg and Sr compositions that are uniquely high for the past 3 kyr. Trace element compositions close to the boundary between original aragonite and calcite are consistent with quasi‐equilibrium partitioning of trace elements between the phases. Study of modern dripwaters demonstrates that pronounced covariation of Mg/Ca and Sr/Ca ratios in dripwater occurs owing to large amounts of calcite precipitation upflow of the drips that fed the stalagmites. Trace element to Ca ratios are enhanced during seasonally dry periods. Ion microprobe data demonstrate a pronounced covariation of trace elements, including Mg and Sr in calcite, and Sr, U and Ba in aragonite. The mean peak spacing is close to the long‐term mean of annual growth rates determined by differences in U‐series ages and so the trace element peaks are interpreted as annual. The trace element chemistry of the stalagmites on annual to inter‐annual scales thus directly reflects the amounts of prior calcite precipitation, interpreted as an index of aridity. The longer‐term context is a multi‐decadal period of aridity (1200–1100 yr BP) possibly correlated with an analogous episode in Central America. The arid period culminated in the nucleation of aragonite, but within a decade was followed by a return to precursor conditions. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Early fill of the Western Irish Namurian Basin: a complex relationship between turbidites and deltas   总被引：1，自引：0，他引：1  

John D. Collinson  Ole Martinsen  Bente Bakken  Anne Kloster 《Basin Research》1991,3(4):223-242

The Western Irish Namurian Basin developed in Early Carboniferous times as a result of extension across the Shannon Lineament which probably coincides with the lapetus Suture. During the late Dinantian, axial areas of the NE-SW elongate trough became deep, whilst shallow-water limestones were deposited on the flanks. This bathymetry persisted into the Namurian when carbonate deposition ceased. In axial areas, a relatively thick mudstone succession spans earliest Namurian to Chokierian whilst on the northwestern marginal shelf, a thin, condensed Namurian mudstone sequence, in which pre-Chokierian sediments are apparently absent, rests unconformably on the Dinantian. From late Chokierian to early Kinderscoutian, the basin was filled by sand-dominated clastic sediments. Sand deposition began in the axial area with deposition of a thick turbidite sequence, the Ross Formation, which is largely equivalent to the condensed mudstone succession on the flanks. Turbidity currents flowed mainly axially towards the north-east and deposited a sequence lacking well-defined patterns of vertical bed-thickness change. Channels and slide sheets occur towards the top of the formation. The turbidite system seems to have lacked well-defined lobes and stable distributary channels. Overlying the Ross Formation, the Gull Island Formation shows a decreasing incidence of turbidite sandstones at the expense of increasing siltstones. This formation is characterized by major slides and slumps interbedded with undisturbed strata. In the flanking areas of the basin, the formation is thinner, has only a few turbidites in the sequence above the condensed mudstones and contains only one slide sheet. Overall the formation is interpreted as the deposit of a major prograding slope, the lower part representing a ramp upon which turbidites were deposited, the upper part a highly unstable muddy slope lacking any conspicuous feeder channels through which sand might have been transferred to deeper water. Progradation of the slope appears to have been increasingly from the northwestern flank of the trough which is similar to the direction deduced for the overlying deltaic Tullig cyclothem which completes the initial basin fill. Whilst several features of the succession can be explained by envisaging the whole sequence as the product of one linked depositional system, the shifting directions of palaeocurrents and palaeoslope raise problems. The switch from axial to lateral supply casts doubt on the strict application of Walther's Law to the total sequence and seems to demand large avulsive shifts of the delta system on the shelf area to the west.  相似文献   

The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica     

Joseph A. Shacat  William J. Green  Eric H. Decarlo  Silvia Newell 《Aquatic Geochemistry》2004,10(3-4):325-352

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.  相似文献   

Nickel, Copper, Zinc and Cadmium Cycling with Manganese in Lake Vanda (Wright Valley, Antarctica)     

William J. Green  Brian R. Stage  Bonnie Jo Bratina  Shannon Wagers  Adam Preston  Kevin O’bryan  Joseph Shacat  Silvia Newell 《Aquatic Geochemistry》2004,10(3-4):303-323

Lake Vanda is a closed-basin, permanently ice-covered lake located in the Wright Valley of Antarctica. The lakes more important geochemical features include the fact that it is fed by a single glacial melt water stream for only 6–8weeks out of the year; that it has remained stratified for more than a millennium; and that, like other lakes in the region, it is remote from anthropogenic influence. These, together with the fact that it is among the least biologically productive lakes in the world, make it an ideal system for examining the transport, cycling and fate of trace metals in the aquatic environment. Like others before us, we view this lake as a natural geochemical laboratory, a flask in the desert. This paper presents the first set of closely spaced, vertical, profiles for dissolved and particulate Mn, Fe, Ni, Cu, Zn and Cd in the water column. Despite the absence of an outflow, metals in the fresh upper waters of the lake have extremely low concentrations, in the pico-molar to nano-molar range, and are partitioned largely into dissolved rather than particulate phases. Efficient metal scavenging by particles from these oxygen-rich waters is indicated. Significant increases in metal concentrations begin to appear at depth, between 57 and 60m, and these increases coincide with the onset of manganese oxide dissolution in oxic, but lower pH waters. Vertical profiles suggest that the entire suite of trace metals (Ni, Cu, Zn, and Cd) is being released from manganese oxide carrier phases. Thermodynamic analysis indicates that Mn3O4 (i.e., the mineral hausmannite) may be important in metal sequestration and recycling in the deeper waters of Lake Vanda. Manganese-reducing organisms reported by Bratina etal. (1998) are active in the zone of metal release and these could also contribute to the observed cycling.  相似文献   

1999年欧洲圣诞节风暴数值模拟分析     

Claudio Cassardo  ;Nicola Loglisci  ;Min Wei Qian  ;Silvia Ferrarese  ;Arnaldo Longhetto  ;Gianpaolo Balsamo 《气象与减灾研究》2008,31(2):6-13

对1999年圣诞期间发生在欧洲中西部的圣诞节风暴进行了分析,认为4个主要的低气压系统中的第二个给法国北部带来了强风暴雨,巴黎的Orly机场阵风速度〉47m／s;第四个低压系统沿法国西海岸产生相似的恶劣天气,并在西班牙的北部海岸及地中海沿岸国家造成了毁灭性的破坏。在法国中部风暴最剧烈的时候,最大阵风〉41m／s;在法国和德国之间的区域,达55m／s。圣诞节风暴造成欧洲国家大约140人死亡,其他损失包括树木、街道和房屋被毁,电力系统和电话中断时间长达数天,受影响的人数大约为1000万,财产损失大约为80亿美元。由于风暴的极端强度和快速发展速度,欧洲大多数国家的数值预报中心没有对这次剧烈天气提供足够的预警。为此,利用中尺度数值预报系统（RAMS）模拟圣诞节风暴,并与ECMWF分析资料以及实况观测资料进行了对比分析。结果表明,RAMS模式能够准确模拟风暴的主要特性、低气压的演变和位置移动、发展的关键时间点、风暴演化期间的平均风场;模拟的平均风场和气象观测网的观测结果相一致;模拟的风暴移动时间和主要新闻媒体的报道相吻合;模式计算的一些特定地区平均风速的时间趋势显示,在阿尔卑斯山脉地区,无论是上风区还是下风区,风暴的时间都被准确地预测;模拟的第一次风暴最低气压值较实际值偏低。  相似文献   

The gravitational wave background from star–massive black hole fly-bys     

Silvia Toonen  Clovis Hopman  Marc Freitag 《Monthly notices of the Royal Astronomical Society》2009,398(3):1228-1234

Stars on eccentric orbits around a massive black hole (MBH) emit bursts of gravitational waves (GWs) at periapse. Such events may be directly resolvable in the Galactic Centre. However, if the star does not spiral in, the emitted GWs are not resolvable for extragalactic MBHs, but constitute a source of background noise. We estimate the power spectrum of this extreme mass ratio burst background (EMBB) and compare it to the anticipated instrumental noise of the Laser Interferometer Space Antenna (LISA). To this end, we model the regions close to an MBH, accounting for mass segregation, and for processes that limit the presence of stars close to the MBH, such as GW inspiral and hydrodynamical collisions between stars. We find that the EMBB is dominated by GW bursts from stellar mass black holes, and the magnitude of the noise spectrum  ( fS _GW)^1/2  is at least a factor of ∼10 smaller than the instrumental noise. As an additional result of our analysis, we show that LISA is unlikely to detect relativistic bursts in the Galactic Centre.  相似文献   

Hydrostatic gas distributions: global estimates of temperature and abundance     

Luca Ciotti  Silvia Pellegrini 《Monthly notices of the Royal Astronomical Society》2008,387(2):902-914

Estimating the temperature and metal abundance of the intracluster and the intragroup media is crucial to determine their global metal content and to determine fundamental cosmological parameters. When a spatially resolved temperature or abundance profile cannot be recovered from observations (e.g. for distant objects), or deprojection is difficult (e.g. due to a significant non-spherical shape), only global average temperature and abundance are derived. After introducing a general technique to build hydrostatic gaseous distributions of prescribed density profile in potential wells of any shape, we compute the global mass-weighted and emission-weighted temperature and abundance for a large set of barotropic equilibria and an observationally motivated abundance gradient. We also compute the spectroscopic-like temperature that is recovered from a single temperature fit of observed spectra. The derived emission-weighted abundance and temperatures are higher by 50 to 100 per cent than the corresponding mass-weighted quantities, with overestimates that increase with the gas mean temperature. Spectroscopic temperatures are intermediate between mass and luminosity-weighted temperatures. Dark matter flattening does not lead to significant differences in the values of the average temperatures or abundances with respect to the corresponding spherical case (except for extreme cases).  相似文献   

Precipitation in the Karakoram-Himalaya: a CMIP5 view     

Elisa Palazzi  Jost von Hardenberg  Silvia Terzago  Antonello Provenzale 《Climate Dynamics》2015,45(1-2):21-45

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Subsidence and thermal history of an inverted Late Jurassic‐Early Cretaceous extensional basin (Cameros,North‐central Spain) affected by very low‐ to low‐grade metamorphism          下载免费PDF全文

Silvia Omodeo‐Salé  Ramon Salas  Joan Guimerà  Robert Ondrak  Ramon Mas  José Arribas  Isabel Suárez‐Ruiz  Luis Martinez 《Basin Research》2017,29(Z1):156-174

The Cameros Basin (North Spain) is a Late Jurassic‐Early Cretaceous extensional basin, which was inverted during the Cenozoic. It underwent a remarkable thermal evolution, as indicated by the record of anomalous high temperatures in its deposits. In this study, the subsidence and thermal history of the basin is reconstructed, using subsidence analysis and 2D thermal modelling. Tectonic subsidence curves provide evidence of the occurrence of two rapid subsidence phases during the syn‐extensional stage. In the first phase (Tithonian‐Early Berriasian), the largest accommodation space was formed in the central sector of the basin, whereas in the second (Early Barremian‐Early Albian), it was formed in the northern sector. These rapid subsidence phases could correspond to relevant tectonic events affecting the Iberian Plate at that time. By distinguishing between the initial and thermal subsidence and defining their relative magnitudes, Royden's (1986) method was used to estimate the heat flow at the end of the extensional stage. A maximum heat flow of 60–65 mW/m² is estimated, implying only a minor thermal disturbance associated with extension. In contrast with these data, very high vitrinite reflectance, anomalously distributed in some case with respect to the typical depth‐vitrinite reflectance relation, was measured in the central‐northern sector of the basin. Burial and thermal data are used to construct a 2D thermal basin model, to elucidate the role of the processes involved in sediment heating. Calibration of the thermal model with the vitrinite reflectance (%Ro) and fluid inclusion (FI) data indicates that in the central and northern sectors of the basin, an extra heat source, other than a typical rift, is required to explain the observed thermal anomalies. The distribution of the %Ro and FI values in these sectors suggests that the high temperatures and their distribution are related to the circulation of hot fluids. Hot fluids were attributed to the hydrothermal metamorphic events affecting the area during the early post‐extensional and inversion stages of the basin.  相似文献   

Comparative study of As,Cd, Cu,Cr, Mg,Mn, Ni,Pb and Zn concentrations between sediment and water from estuary and port     

I. Bejarano-Ramirez  Jose M. Jurado  R. Muñiz-Valencia  Á. Alcázar  Silvia G. Ceballos-Magaña  A. Olivos-Ortiz  O. Rangel 《International Journal of Environmental Science and Technology》2017,14(6):1333-1342

The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献